Publications

nature comm

Mechanistic manifold in a hemoprotein-catalyzed cyclopropanation reaction with diazoketone

Donggeon Nam, John-Paul Bacik, Rahul L. Khade, Maria Camila Aguilera, Yang Wei, Juan D. Villada, Michael L. Neidig, Yong Zhang, Nozomi Ando & Rudi Fasan

 Nature Communications, 2023, 14, 7985

                                                                                         DOI: 10.1038/s41467-023-43559-7

 

 

palladium and iron cocatalyzed aerobic alkene aminoboration

 

Palladium and Iron Cocatalyzed Aerobic Alkene Aminoboration

Gay, B. L., Wang, Y., Bhatt, S., Tarasewicz, A., Cooke, D. J., Milem, E. G., Zhang, B., Gary, J. B., Neidig, M. L., & Hull, K. L.

J. Am. Chem. Soc. 2023, 145, 18939–18947.

DOI: 10.1021/jacs.3c05790

 

mechanistic studies of iron pybox catalyzed olefin amino oxygenation with functionalized hydroxylamines

 

Mechanistic Studies of Iron-PyBOX-Catalyzed Olefin Amino-Oxygenation with Functionalized Hydroxylamines

Radović, A.; Wolford, N. J.; Li, W.; Brennessel, W. W.; Xu, H.; Neidig, M. L.

Organometallics. 2023, 42, 1810–1817.

DOI: 10.1021/acs.organomet.3c00067

insight into radical initiation solvent effects and biphenyl production in iron bisphosphine cross couplings

 

Insight into Radical Initiation, Solvent Effects, and Biphenyl Production in Iron–Bisphosphine Cross-Couplings

Aguilera, M. C.; Gogoi, A. R.; Lee, W.; Liu, L.; Brennessel, W. W.; Gutierrez, O.; Neidig, M. L.

ACS Catal. 2023, 13, 8987–8996.

DOI: 10.1021/acscatal.3c02008

thermally stable redox noninnocent bathocuproine iron complex for cycloaddition reactions

 

Thermally Stable Redox Noninnocent Bathocuproine-Iron Complex for Cycloaddition Reactions

Féo, M.; Bakas, N. J.; Radović, A.; Parisot, W.; Clisson, A.; Chamoreau, L.; Mansour, Ratovelomanana-Vidal, V.,;Neidig, M. L.; Lefèvre, G. 

ACS Catal. 2023, 13, 4882–4893.

DOI: 10.1021/acscatal.3c00353

 

the molecular level effect of alkoxide additives in iron catalyzed kumada cross coupling with simple ferric salts 3

 

The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts

Bakas, N. J.; Chourreu P.; Gayon, E.; Lefèvre, G.; Neidig, M. L.

Chem. Commun. 2023, 59, 1317-1320 

DOI: 10.1039/D2CC06257G

challenges and opportunities of fe based core shell catalysts for fischer tropsch synthesis

 

 

Challenges and Opportunities of Fe-based Core-Shell Catalysts for Fischer-Tropsch Synthesis

Agwara, J. N.; Bakas, N. J.; Neidig, M. L.; & Porosoff, M. D. 

ChemCatChem 2022, 14, e202200289.

DOI: 10.1002/cctc.202200289

real homoleptic uranium bisacyl

 

Homoleptic Uranium–Bis(acyl)phosphide Complexes

Carpenter, S. H.; Wolford, N. J.; Billow, B. S.; Fetrow, T. V.; Cajiao, N.; Radović, A.; Janicke, M. T.; Neidig, M. L.; & Tondreau, A. M.

Inorg. Chem. 2022, 61, 12508–12517.

DOI: 10.1021/acs.inorgchem.2c00639

anion induced disproportionation of thiii complexes to form thii and thiv products

Anion-induced disproportionation of Th(III) complexes to form Th(II) and Th(IV) products

Wedal, J. C.; Cajiao, N.; Neidig, M. L.; & Evans, W. J.

Chem. Commun. 2022, 58, 5289-5291.

                                                                                        DOI: 10.1039/D2CC01272C

a tmeda iron adduct reaction manifold in iron catalyzed csp2csp3 cross coupling reactions

 

 

A TMEDA–Iron Adduct Reaction Manifold in Iron-Catalyzed C(sp2)−C(sp3) Cross-Coupling Reactions

Bakas, N. J.; Sears, J. D.; Brennessel, W. W.; Neidig M. L.

Angew. Chem. Int. Ed. 2022, 61, e202114986

DOI: 10.1002/anie.202114986

comprehensive organometallic chemistry iv 1

 

Recent Advances in Synthesis, Characterization and Reactivities of Iron-Alkyl and Iron-Aryl Complexes

Zhang, B.; Aguilera, M.C.; Cajiao, N.; Neidig, M.L.

Comprehensive Organometallic Chemistry IV: Volume 1-15. 2022, 185–209

DOI: 10.1016/B978-0-12-820206-7.00084-6

comprehensive organometallic chemistry iv 1

 

Characterization Methods for Paramagnetic Organometallic Complexes

Radović, A.; Bhatia, S.; Neidig, M.L.

Comprehensive Organometallic Chemistry IV: Volume 1-15. 2022, 135–175

DOI: 10.1016/B978-0-12-820206-7.00059-7

intermediates and mechanism in iron catalyzed c h methylation with trimethylaluminum

 

Intermediates and mechanism in iron-catalyzed C–H methylation with trimethylaluminum

Bathia, S.; DeMuth, J.C.; Neidig M. L.

Chem. Commun. 2021, 57, 12784-12787 

 DOI: 10.1039/D1CC05607G

nature communications

Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes

Gaiser, A. N.; Celis-Barros, C.; White, F. D.; Beltrán-Leiva, M. J.; Sperling, J.; Salpage, S. R.; Poe, T. N.; Martinez, D. G.; Jian, T., Wolford, N. J.; Neidig, M. L., & Albrecht‐Schönzart, T. E.; et al.

Nat Commun. 2021, 12, 7230

DOI: 10.1038/s41467-021-27576-y

air stable iron based precatalysts for suzuki miyaura cross coupling reactions between alkyl halides and aryl boronic esters

 

Air-Stable Iron-Based Precatalysts for Suzuki–Miyaura Cross-Coupling Reactions between Alkyl Halides and Aryl Boronic Esters

Wong, A. K. K.; Zhang, B.; Li, B.; Neidig, M. L.; & Byers, J. A.

Org. Process Res. Dev. 2021, 25, 2461–2472

DOI: 10.1021/acs.oprd.1c00235

general method for iron catalyzed multicomponent radical cascades cross couplings

 

General method for iron-catalyzed multicomponent radical cascades–cross-couplings

Liu, L.; Aguilera, M. C.; Lee, W.; Youshaw, C. R.; Neidig, M. L.; Gutierrez, O.

Science 2021, 374, 432–439

DOI: 10.1126/science.abj6005

nhc effects on reduction dynamics in iron catalyzed organic transformations

NHC Effects on Reduction Dynamics in Iron-Catalyzed Organic Transformations

Wolford, N. J.; Muñoz, S. B.; Neate, P. G. N.; Brennessel, W. W.; Neidig, M. L.

Chem. Eur. J. 2021, 27, 13651–13658

                                                                                       DOI: 10.1002/chem.202102070

2fe 2s cluster supported by redox active o phenylenediamide ligands and its application toward dinitrogen reduction

 

Cluster Supported by Redox-Active o-Phenylenediamide Ligands and Its Application toward Dinitrogen Reduction

Liang, Q.; DeMuth, J.; Radović, A.; Wolford, N. J.; Neidig, M. L.; & Song, D.

Inorg. Chem. 2021, 60, 13811–13820

DOI: 10.1021/acs.inorgchem.1c00683

chemcatalysis

 

An anionic iron-hydride superstar for the isomerization of terminal alkenes

Aguilera, M.C.; Neidig, M.L.

Chem Catal. 2021, 1, 488–489

DOI: 10.1016/j.checat.2021.07.009

dilithium amides as a modular bis anionic ligand platform for iron catalyzed cross coupling

 

Dilithium Amides as a Modular Bis-Anionic Ligand Platform for Iron-Catalyzed Cross-Coupling

Neate, P. G. N.; Zhang, B.; Conforti, J.; Brennessel, W. W.; Neidig, M. L.

Org. Lett. 2021, 23, 5958–5963

DOI: 10.1021/acs.orglett.1c02053

comprehensive coordination chemistry iii

 

Metal-carbon bonds of iron and manganese

Neidig, M.L., Bakas, N.J., Neate, P.G.N., Sears, J.D.

Comprehensive Coordination Chemistry III. 2021, 82–122

DOI: 10.1016/B978-0-08-102688-5.00050-7

comprehensive coordination chemistry iii

 

C-H activation/functionalization with earth abundant 3d transition metals

Neidig, M.L., DeMuth, J.C., Zhang, B.

Comprehensive Coordination Chemistry III. 2021, 260–310

DOI: 10.1016/B978-0-08-102688-5.00009-X

functionalisation with allyl electrophiles

Experimental and computational studies of the mechanism of iron-catalysed C-H activation/functionalisation with allyl electrophiles

DeMuth, J. C.; Song, Z.; Carpenter, S. H.; Boddie, T. E.; Radović, A.; Baker, T. M.; Gutierrez, O.; Neidig, M. L.

Chem. Sci. 2021, 12, 9398–9407

DOI: 10.1039/D1SC01661J

near infrared c term mcd spectroscopy of octahedral uraniumv complexes

 

Near-infrared C-term MCD spectroscopy of octahedral uranium(v) complexes

Curran, D. J.; Ganguly, G.; Heit, Y. N.; Wolford, N. J.; Minasian, S. G.; Löble, M. W.; Cary, S. K.; Kozimor, S. A.; Autschbach, J.; Neidig, M. L.

Dalton Trans. 2021, 50, 5483–5492

DOI: 10.1039/D1DT00513H

nature review chem

 

Forged in iron

Neate, P. G. N.; Neidig, M. L.

Nat Rev Chem. 2021, 5, 223–224

DOI: 10.1038/s41570-021-00259-4

chemsci

Activation of ammonia and hydrazine by electron rich Fe(II) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(III) amido intermediate

Nurdin, L.; Yang, Y.; Neate, P. G. N.; Piers, W. E.; Maron, L.; Neidig, M. L.; Lin, J.; Gelfand, B. S.

Chem. Sci. 2021,12, 2231-2241 

                                                                                       DOI: 10.1039/D0SC06466A

homoleptic uranium bisacylphosphide complexe

 

C-Term Magnetic Circular Dichroism (MCD) Spectroscopy in Paramagnetic Transition Metal and f-Element Organometallic Chemistry

Wolford, N. J.; Radovic, A.; Neidig, M. L.

Dalton Trans. 2021, 50, 416–428

DOI: 10.1039/D0DT03730C

additive and counterion effects in iron catalyzed reactions relevant to c c bond formation

Additive and Counterion Effects in Iron-Catalyzed Reactions Relevant to C–C Bond Formation

Bakas, N. J.; Neidig, M. L.

ACS Catal. 2021, 11, 8493–8503

DOI: 10.1021/acscatal.1c00928

catalysis with earth abundant elements

 

CHAPTER 7: Open Shell Iron Catalysis: Mechanistic Challenges, Approaches and Pitfalls

Neate, P.G.N.; Neidig, M.L.

RSC Catalysis Series. 2021, 231–245

DOI: 10.1039/9781788012775-00231

ligand effects on electronic structure and bonding in uiii coordination complexes

Ligand Effects on Electronic Structure and Bonding in U(III) Coordination Complexes: A Combined MCD, EPR and Computational Study

Wolford, N. J.; Yu, X.; Bart, S. C.; Autschbach, J.; Neidig, M. L.

Dalton Trans. 2020, 49, 14401–14410

DOI: 10.1039/D0DT02929G

daltontrans

Syntheses and characterizations of iron complexes of bulky: O-phenylenediamide ligand

Liang, Q.; Lin, J.H.; Demuth, J.C.; Neidig, M.L.; Song, D.

Dalton Trans. 2020, 49, 12287-12297 

DOI: 10.1039/D0DT02087G

tmeda in iron catalyzed hydromagnesiation formation of ironii alkyl species for controlled reduction to alkene stabilized iron0

 

TMEDA in Iron‐Catalyzed Hydromagnesiation: Formation of Iron(II)‐Alkyl Species for Controlled Reduction to Alkene‐Stabilized Iron(0)

Neate, P. G. N.; Greenhalgh, M. D.; Brennessel, W. W.; Thomas, S. P.; Neidig, M. L.

Angew. Chem. Int. Ed. 2020, 59, 17070–17076

DOI: 10.1002/anie.202006639

the exceptional diversity of homoleptic uranium methyl complexes 2

 

The Exceptional Diversity of Homoleptic Uranium–Methyl Complexes

Sears, J. D.; Sergentu, D.; Baker, T. M.; Brennessel, W. W.; Autschbach, J.; Neidig, M. L.

Angew. Chem. Int. Ed. 2020, 59, 13586–13590

DOI: 10.1002/anie.202005138

identifying correlations in fischer tropsch synthesis and co2 hydrogenation over fe based zsm 5 catalysts

Identifying correlations in Fischer-Tropsch synthesis and CO2 hydrogenation over Fe-based ZSM-5 catalysts

Liu, R.; Ma, Z.; Sears, J. D.; Juneau, M.; Neidig, M. L.; Porosoff, M. D.

J. CO2 Util. 2020, 41, 101290

DOI: 10.1016/j.jcou.2020.101290

isolation and characterization of a homoleptic tetramethylcobaltiii distorted square planar complex

 

Isolation and Characterization of a Homoleptic Tetramethylcobalt(III) Distorted Square-Planar Complex

Carpenter, S.H.; Brennessel, W.W.; Neidig, M.L.

Organometallics 2019, 38, 3486–3489

DOI: 10.1021/acs.organomet.9b00387

insight into the electronic structure of formal lanthanideii complexes using magnetic circular dichroism spectroscopy

 

Insight into the Electronic Structure of Formal Lanthanide(II) Complexes Using Magnetic Circular Dichroism Spectroscopy

Fleischauer, V. E.; Ganguly, G.; Woen, D. H.; Wolford, N. J.; Evans, W. J.; Autschbach, J.; Neidig, M. L.

Organometallics 2019, 38, 3124–3131

DOI: 10.1021/acs.organomet.9b00315

atom economical ni catalyzed diborylative cyclization of enynes preparation of unsymmetrical diboronates

Atom-Economical Ni-Catalyzed Diborylative Cyclization of Enynes: Preparation of Unsymmetrical Diboronates

Cabrera‐Lobera, N., Quirós, M. T., Brennessel, W. W., Neidig, M. L., Buñuel, E., & Cárdenas, D. J.

Org. Lett. 2019, 21, 6552–6556

DOI: 10.1021/acs.orglett.9b02485

identification and reactivity of cyclometalated ironii intermediates in triazole directed iron catalyzed c h activation

Identification and Reactivity of Cyclometalated Iron(II) Intermediates in Triazole-Directed Iron-Catalyzed C–H Activation

Boddie, T. E.; Carpenter, S. H.; Baker, T. M.; DeMuth, J. C.; Cera, G.; Brennessel, W. W.; Ackermann, L.; Neidig, M. L.

J. Am. Chem. Soc. 2019, 141, 12338–12345

DOI: 10.1021/jacs.9b05269

homoleptic aryl complexes of uranium iv 2

 

Homoleptic Aryl Complexes of Uranium (IV)

Wolford, N. J.; Sergentu, D.; Brennessel, W. W.; Autschbach, J.; Neidig, M. L.

Chem. Int. Ed. 2019, 58 (30), 10266–10270

DOI: 10.1002/anie.201905423

mechanism of the bisiminopyridine iron catalyzed hydromagnesiation of styrene derivatives

 

Mechanism of the Bis(Imino)Pyridine-Iron-Catalyzed Hydromagnesiation of Styrene Derivatives

Neate, P. G. N.; Greenhalgh, M. D.; Brennessel, W. W.; Thomas, S. P.; Neidig, M. L.

J. Am. Chem. Soc. 2019, 141, 10099–10108

DOI: 10.1021/jacs.9b04869

the effect of v hydrogen atoms on iron speciation in cross couplings with simple iron salts and alkyl grignard reagents

The Effect of β‐Hydrogen Atoms on Iron Speciation in Cross‐Couplings with Simple Iron Salts and Alkyl Grignard Reagents

Sears, J. D.; Muñoz, S. B.; Daifuku, S. L.; Shaps, A. A.; Carpenter, S. H.; Brennessel, W. W.; Neidig, M. L.

Angew. Chem. Int. Ed. 2019, 58, 2769–2773

DOI: 10.1002/anie.201813578

development and evolution of mechanistic understanding in iron catalyzed cross coupling

Development and Evolution of Mechanistic Understanding in Iron-Catalyzed Cross-Coupling

Neidig, M. L.; Carpenter, S. H.; Curran, D. J.; DeMuth, J. C.; Fleischauer, V. E.; Iannuzzi, T. E.; Neate, P. G. N.; Sears, J. D.; Wolford, N. J.

Acc. Chem. Res. 2019, 52, 140–150

DOI: 10.1021/acs.accounts.8b00519

synthesis and characterization of a sterically encumbered homoleptic tetraalkylironiii ferrate complex

Synthesis and Characterization of a Sterically Encumbered Homoleptic Tetraalkyliron(III) Ferrate Complex

Sears, J. D.; Muñoz, S. B.; Cuenca, M. C. A.; Brennessel, W. W.; Neidig, M. L.

Polyhedron 2019, 158, 91–96

DOI: 10.1016/j.poly.2018.10.041

general method for iron catalyzed multicomponent radical cascades cross couplings

 

Terminal Coordination of Diatomic Boron Monofluoride to Iron

Drance, M. J.; Sears, J. D.; Mrse, A. M.; Moore, C. E.; Rheingold, A. L.; Neidig, M. L.; Figueroa, J. S.

Science 2019, 363, 1203–1205

DOI: 10.1126/science.aaw6102

acta cryst e

 

Crystal structure of bromidopentakis(tetrahydrofuran-κ O)magnesium bis[1,2-bis(diphenylphosphanyl)benzene-κ2P, P ′]cobaltate(-1) tetrahydrofuran disolvate

Girigiri, P.B.; Carpenter, S.H.; Brennessel, W.W.; Neidig, M.L.

Acta Crystallogr. E: Crystallogr. Commun. 2019, 75, 304–307

DOI: 10.1107/S2056989019001671

intermediates and mechanism in iron catalyzed cross coupling

 

 

Intermediates and Mechanism in Iron-Catalyzed Cross-Coupling

Sears, J. D.; Neate, P. G. N.; Neidig, M. L.

J. Am. Chem. Soc. 2018, 140 (38), 11872–11883

DOI: 10.1021/jacs.8b06893

combined effects of backbone and n substituents on structure bonding and reactivity of alkylated ironii nhcs

 

Combined Effects of Backbone and N-Substituents on Structure, Bonding, and Reactivity of Alkylated Iron(II)-NHCs

Muñoz, S. B.; Fleischauer, V. E.; Brennessel, W. W.; Neidig, M. L.

Organometallics 2018, 37, 3093–3101

DOI: 10.1021/acs.organomet.8b00466

backbone dehydrogenation in pyrrole based pincer ligands

 

Backbone Dehydrogenation in Pyrrole-Based Pincer Ligands

Krishnan, V. M.; Davis, I.; Baker, T. M.; Curran, D. J.; Arman, H. D.; Neidig, M. L.; Liu, A.; Tonzetich, Z. J.

Inorg. Chem. 2018, 57, 9544–9553

DOI: 10.1021/acs.inorgchem.8b01643

a pseudotetrahedral uraniumv complex

 

A Pseudotetrahedral Uranium(V) Complex

Tondreau, A. M.; Duignan, T. J.; Stein, B. W.; Fleischauer, V. E.; Autschbach, J.; Batista, E. R.; Boncella, J. M.; Ferrier, M. G.; Kozimor, S. A.; Mocko, V.; Neidig, M. L.; Cary, S. K.; Yang, P.

Inorg. Chem. 2018, 57, 8106–8115

DOI: 10.1021/acs.inorgchem.7b03139

the n methylpyrrolidone nmp effect in iron catalyzed cross coupling with simple ferric salts and memgbr

The N-Methylpyrrolidone (NMP) Effect in Iron‐Catalyzed Cross‐Coupling with Simple Ferric Salts and MeMgBr

Muñoz, S. B.; Daifuku, S. L.; Sears, J. D.; Baker, T. M.; Carpenter, S. H.; Brennessel, W. W.; Neidig, M. L.

Chem. Int. Ed. 2018, 57, 6496

DOI: 10.1002/anie.201802087

nhc and nucleophile chelation effects on reactive ironii species in alkyl alkyl cross coupling

 

NHC and Nucleophile Chelation Effects on Reactive Iron(II) Species in Alkyl–Alkyl Cross-Coupling

Fleischauer, V. E.; Muñoz III, S. B.; Neate, P. G. N.; Brennessel, W. W.; Neidig, M. L.

Chem. Sci. 2018, 9, 1878–1891

DOI: 10.1039/C7SC04750A

multinuclear iron phenyl species in reactions of simple iron salts with phmgbr identification of fe4m ph6thf4

Multinuclear Iron–Phenyl Species in Reactions of Simple Iron Salts with PhMgBr: Identification of Fe4(μ-Ph)6(THF)4

Carpenter, S. H.; Baker, T. M.; Muñoz, S. B.; Brennessel, W. W.; Neidig, M. L.

Chem. Sci. 2018, 9, 7931–7939

DOI: 10.1039/C8SC02915F

chemsci

Nitric Oxide Activation Facilitated by Cooperative Multimetallic Electron Transfer within an Iron-Functionalized Polyoxovanadate–Alkoxide Cluster

Li, F.; Meyer, R. L.; Carpenter, S. H.; VanGelder, L. E.; Nichols, A. W.; Machan, C. W.; Neidig, M. L.; Matson, E.

Chem. Sci. 2018, 9, 6379–6389

DOI: 10.1039/C8SC00987B

acta cryst e

 

Crystal structures of two new six-coordinate iron(III) complexes with 1,2-bis(diphenylphosphane) ligands

McNeil, D. L., Beckford, D. J., Kneebone, J. L., Carpenter, S. H., Brennessel, W. W., & Neidig, M. L.

Acta Crystallogr. E: Crystallogr. Commun. 2018, 74, 803–807

DOI: 10.1107/S2056989018006898

a physical inorganic approach for the elucidation of active iron species and mechanism in iron catalyzed cross coupling 2

 

A Physical-Inorganic Approach for the Elucidation of Active Iron Species and Mechanism in Iron-Catalyzed Cross-Coupling

Carpenter, S. H.; Neidig, M. L.

Isr. J. Chem. 2017, 57, 1106–1116

DOI: 10.1002/ijch.201700036

ironii complexes of a hemilabile sns amido ligandsynthesis characterization and reactivity

 

Iron(II) Complexes of a Hemilabile SNS Amido Ligand: Synthesis, Characterization, and Reactivity

Das, U. K.; Daifuku, S. L.; Iannuzzi, T. E.; Gorelsky, S. I.; Korobkov, I.; Gabidullin, B.; Neidig, M. L.; Baker, R. T.

Inorg. Chem. 2017, 56, 13766–13776

DOI: 10.1021/acs.inorgchem.7b01802

a combined probe molecule mossbauer nuclear resonance vibrational spectroscopy and density functional theory

A Combined Probe-Molecule, Mössbauer, Nuclear Resonance Vibrational Spectroscopy, and Density Functional Theory Approach for Evaluation of Potential Iron Active Sites in an Oxygen Reduction Reaction Catalyst

Kneebone, J. L.; Daifuku, S. L.; Kehl, J. A.; Wu, G.; Chung, H. T.; Hu, M. Y.; Alp, E. E.; More, K. L.; Zelenay, P.; Holby, E. F.; Neidig, M. L.

J. Phys. Chem. C. 2017, 121, 16283–16290

DOI: 10.1021/acs.jpcc.7b03779

polyoxovanadate alkoxide clusters as a redox reservoir for iron

 

Polyoxovanadate–Alkoxide Clusters as a Redox Reservoir for Iron

Li, F.; Carpenter, S. H.; Higgins, R. F.; Hitt, M. G.; Brennessel, W. W.; Ferrier, M. G.; Cary, S. K.; Lezama-Pacheco, J. S.; Wright, J. T.; Stein, B. W.; Shores, M. P.; Neidig, M. L.; Kozimor, S. A.; Matson, E. M.

Inorg. Chem. 2017, 56, 7065–7080

DOI: 10.1021/acs.inorgchem.7b00650

intermediates and reactivity in iron catalyzed cross couplings of alkynyl grignards with alkyl halides

 

Intermediates and Reactivity in Iron-Catalyzed Cross-Couplings of Alkynyl Grignards with Alkyl Halides

Kneebone, J. L.; Brennessel, W. W.; Neidig, M. L.

J. Am. Chem. Soc. 2017, 139, 6988–7003

DOI: 10.1021/jacs.7b02363

transition metal free formation of c e bonds

Transition-Metal-Free Formation of C–E Bonds (E = C, N, O, S) and Formation of C–M Bonds (M = Mn, Mo) from N -Heterocyclic Carbene Mediated Fluoroalkene C–F Bond Activation

Leclerc, M. C.; Gabidullin, B. M.; Da Gama, J. G.; Daifuku, S. L.; Iannuzzi, T. E.; Neidig, M. L.; Baker, R. T.

Organometallics 2017, 36, 849–857

                                                                                       DOI: 10.1021/acs.organomet.6b00908

daltontrans

Magnetic Circular Dichroism and Density Functional Theory Studies of Electronic Structure and Bonding in Cobalt(II)–N-Heterocyclic Carbene Complexes

Iannuzzi, T. E.; Gao, Y.; Baker, T. M.; Deng, L.; Neidig, M. L.

Dalton Trans. 2017, 46, 13290–13299

DOI: 10.1039/C7DT01748K

pccp

Magnetic Circular Dichroism of UCl6− in the Ligand-to-Metal Charge-Transfer Spectral Region

Gendron, F.; Fleischauer, V. E.; Duignan, T. J.; Scott, B. L.; Löble, M. W.; Cary, S. K.; Kozimor, S. A.; Bolvin, H.; Neidig, M. L.; Autschbach, J.

Phys. Chem. Chem. Phys. 2017, 19, 17300–17313

                                                                                      DOI: 10.1039/C7CP02572F

magnetic circular dichroism studies of ironii binding to human calprotectin

 

Magnetic Circular Dichroism Studies of Iron(II) Binding to Human Calprotectin

Baker, T. M.; Nakashige, T. G.; Nolan, E. M.; Neidig, M. L.

Chem. Sci. 2017, 8, 1369–1377

DOI: 10.1039/C6SC03487J

magnetic circular dichroism and density functional theory studies of ironii pincer complexes

Magnetic Circular Dichroism and Density Functional Theory Studies of Iron(II)-Pincer Complexes: Insight into Electronic Structure and Bonding Effects of Pincer N-Heterocyclic Carbene Moieties

Baker, T. M.; Mako, T. L.; Vasilopoulos, A.; Li, B.; Byers, J. A.; Neidig, M. L.

Organometallics 2016, 35, 3692–3700

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resident holes and electrons at organicconductor and organicorganic interfacesan electron paramagnetic resonance investigation

Resident Holes and Electrons at Organic/Conductor and Organic/Organic Interfaces: An Electron Paramagnetic Resonance Investigation

Zhang, C.; Daifuku, S. L.; Neidig, M. L.; Marchetti, A. P.

Org. Electron. 2016, 37, 379–385

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catalytic light driven generation of hydrogen from water by iron dithiolene complexes

 

Catalytic Light-Driven Generation of Hydrogen from Water by Iron Dithiolene Complexes

Lv, H.; Ruberu, T. P. A.; Fleischauer, V. E.; Brennessel, W. W.; Neidig, M. L.; Eisenberg, R.

J. Am. Chem. Soc. 2016, 138, 11654–11663

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manipulating magneto optic properties of a chiral polymer by doping with stable organic biradicals

 

Manipulating Magneto-Optic Properties of a Chiral Polymer by Doping with Stable Organic Biradicals

Lim, C.-K.; Cho, M. J.; Singh, A.; Li, Q.; Kim, W. J.; Jee, H. S.; Fillman, K. L.; Carpenter, S. H.; Neidig, M. L.; Baev, A.; Swihart, M. T.; Prasad, P. N.

Nano Lett. 2016, 16, 5451–5455

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isolation characterization and reactivity of fe8me12

Isolation, Characterization, and Reactivity of Fe8Me12– : Kochi’s S = 1/2 Species in Iron-Catalyzed Cross-Couplings with MeMgBr and Ferric Salts

Muñoz, S. B.; Daifuku, S. L.; Brennessel, W. W.; Neidig, M. L.

J. Am. Chem. Soc. 2016, 138, 7492–7495

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mononuclear dinuclear and trinuclear iron complexes featuring a new monoanionic sns thiolate ligand

 

Mononuclear, Dinuclear, and Trinuclear Iron Complexes Featuring a New Monoanionic SNS Thiolate Ligand

Das, U. K.; Daifuku, S. L.; Gorelsky, S. I.; Korobkov, I.; Neidig, M. L.; Le Roy, J. J.; Murugesu, M.; Baker, R. T.

Inorg. Chem. 2016, 55, 987–997

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electronic structure and bonding in ironii and ironi complexes bearing bisphosphine ligands of relevance to iron catalyzed c c cross coupling

Electronic Structure and Bonding in Iron(II) and Iron(I) Complexes Bearing Bisphosphine Ligands of Relevance to Iron-Catalyzed C–C Cross-Coupling

Kneebone, J. L.; Fleischauer, V. E.; Daifuku, S. L.; Shaps, A. A.; Bailey, J. M.; Iannuzzi, T. E.; Neidig, M. L.

Inorg. Chem. 2016, 55, 272–282

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chemsci

Facile Hydrogen Atom Transfer to Iron(III) Imido Radical Complexes Supported by a Dianionic Pentadentate Ligand

Spasyuk, D. M.; Carpenter, S. H.; Kefalidis, C. E.; Piers, W. E.; Neidig, M. L.; Maron, L.

Chem. Sci. 2016, 7, 5939–5944

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sci reports nature

Possible Demonstration of a Polaronic Bose-Einstein(-Mott) Condensate in UO2(+x) by Ultrafast THz Spectroscopy and Microwave Dissipation

Conradson, S. D.; Gilbertson, S. M.; Daifuku, S. L.; Kehl, J. A.; Durakiewicz, T.; Andersson, D. A.; Bishop, A. R.; Byler, D. D.; Maldonado, P.; Oppeneer, P. M.; Valdez, J. A.; Neidig, M. L.; Rodriguez, G.

Sci Rep 2015, 5, 15278

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ironii active species in iron bisphosphine catalyzed kumada and suzuki miyaura cross couplings of phenyl nucleophiles and secondary alkyl halides

Iron(II) Active Species in Iron–Bisphosphine Catalyzed Kumada and Suzuki–Miyaura Cross-Couplings of Phenyl Nucleophiles and Secondary Alkyl Halides

Daifuku, S. L.; Kneebone, J. L.; Snyder, B. E. R.; Neidig, M. L.

J. Am. Chem. Soc. 2015, 137, 11432–11444

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linear and t shaped ironi complexes supported by n heterocyclic carbene ligands

Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization

Ouyang, Z.; Du, J.; Wang, L.; Kneebone, J. L.; Neidig, M. L.; Deng, L.

Inorg. Chem. 2015, 54, 8808–8816

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daltontrans

Ambivalent Binding between a Radical-Based Pincer Ligand and Iron

Harriman, K. L. M.; Leitch, A. A.; Stoian, S. A.; Habib, F.; Kneebone, J. L.; Gorelsky, S. I.; Korobkov, I.; Desgreniers, S.; Neidig, M. L.; Hill, S.; Murugesu, M.; Brusso, J. L.

Dalton Trans. 2015, 44, 10516–10523

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how innocent are potentially redox non innocent ligands

How Innocent Are Potentially Redox Non-Innocent Ligands? Electronic Structure and Metal Oxidation States in Iron-PNN Complexes as a Representative Case Study

Butschke, B.; Fillman, K. L.; Bendikov, T.; Shimon, L. J. W.; Diskin-Posner, Y.; Leitus, G.; Gorelsky, S. I.; Neidig, M. L.; Milstein, D.

Inorg. Chem. 2015, 54, 4909–4926

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chemsci

A Combined Magnetic Circular Dichroism and Density Functional Theory Approach for the Elucidation of Electronic Structure and Bonding in Three- and Four-Coordinate Iron(II)–N-Heterocyclic Carbene Complexes

Fillman, K. L.; Przyojski, J. A.; Al-Afyouni, M. H.; Tonzetich, Z. J.; Neidig, M. L.

Chem. Sci. 2015, 6, 1178–1188

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acta cryst e

 

Crystal structure of a third polymorph of tris(acetylacetonato-κ2O,O')iron(III)

Baker, T.M., Howard, K.M., Brennessel, W.W., Neidig, M.L.

Acta Crystallogr. E: Crystallogr. Commun. 2015, 71, m228–m229

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isolation and characterization of a tetramethylironiii ferrate

Isolation and Characterization of a Tetramethyliron(III) Ferrate: An Intermediate in the Reduction Pathway of Ferric Salts with MeMgBr

Al-Afyouni, M. H.; Fillman, K. L.; Brennessel, W. W.; Neidig, M. L.

J. Am. Chem. Soc. 2014, 136, 15457–15460

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rcs logo

 

Two- and Three-Coordinate Formal Iron(I) Compounds Featuring Monodentate Aminocarbene Ligands

Mo, Z.; Ouyang, Z.; Wang, L.; Fillman, K. L.; Neidig, M. L.; Deng, L.

Org. Chem. Front. 2014, 1, 1040–1044

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iron phosphine catalyzed cross coupling of tetraorganoborates and related group 13 nucleophiles with alkyl halides

Iron Phosphine Catalyzed Cross-Coupling of Tetraorganoborates and Related Group 13 Nucleophiles with Alkyl Halides

Bedford, R. B.; Brenner, P. B.; Carter, E.; Clifton, J.; Cogswell, P. M.; Gower, N. J.; Haddow, M. F.; Harvey, J. N.; Kehl, J. A.; Murphy, D. M.; Neeve, E. C.; Neidig, M. L.; Nunn, J.; Snyder, B. E. R.; Taylor, J.

Organometallics 2014, 33, 5767–5780

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a combined mossbauer magnetic circular dichroism and density functional theory approach for iron cross coupling catalysis

A Combined Mössbauer, Magnetic Circular Dichroism, and Density Functional Theory Approach for Iron Cross-Coupling Catalysis: Electronic Structure, In Situ Formation, and Reactivity of Iron-Mesityl-Bisphosphines

Daifuku, S. L.; Al-Afyouni, M. H.; Snyder, B. E. R.; Kneebone, J. L.; Neidig, M. L.

J. Am. Chem. Soc. 2014, 136 (25), 9132–9143

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flexible binding of pnp pincer ligands to monomeric iron complexes

Flexible Binding of PNP Pincer Ligands to Monomeric Iron Complexes

Fillman, K. L.; Bielinski, E. A.; Schmeier, T. J.; Nesvet, J. C.; Woodruff, T. M.; Pan, C. J.; Takase, M. K.; Hazari, N.; Neidig, M. L.

Inorg. Chem. 2014, 53, 6066–6072

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chem eur j

Iron Dicarbonyl Complexes Featuring Bipyridine-Based PNN Pincer Ligands with Short Interpyridine C-C Bond Lengths: Innocent or Non-Innocent Ligand?

Zell, T.; Milko, P.; Fillman, K. L.; Diskin-Posner, Y.; Bendikov, T.; Iron, M. A.; Leitus, G.; Ben-David, Y.; Neidig, M. L.; Milstein, D.

Chem. Eur. J. 2014, 20, 4403–4413

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reactivity of nhc2fex2 complexes toward arylborane lewis acids and arylboronates

 

Reactivity of (NHC)2FeX2 Complexes toward Arylborane Lewis Acids and Arylboronates

Dunsford, J. J.; Cade, I. A.; Fillman, K. L.; Neidig, M. L.; Ingleson, M. J.

Organometallics 2014, 33, 370–377

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direct observation of ict cations at the htltransparent semiconductor interface

Direct Observation of ICT Cations at the HTL/Transparent Semiconductor Interface

Daifuku, S. L.; Favaro, C.; Marchetti, A. P.; Neidig, M. L.

Org. Chem. Front. 2014, 15, 3761–3765

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chem eur j

 

Efficient Nazarov Cyclization/Wagner-Meerwein Rearrangement Terminated by a CuII-Promoted Oxidation: Synthesis of 4-Alkylidene Cyclopentenones

Lebœuf, D.; Theiste, E.; Gandon, V.; Daifuku, S. L.; Neidig, M. L.; Frontier, A. J.

Chem. Eur. J. 2013, 19, 4842–4848

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coord chem rev

 

Covalency in F-Element Complexes

Neidig, M. L.; Clark, D. L.; Martin, R. L.

Coord. Chem. Rev. 2013, 394–406

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Covalency in F-Element Complexes

Neidig, M. L.; Clark, D. L.; Martin, R. L.

Coord. Chem. Rev. 2013, 394–406

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