Publications
Effective Alkyl-Alkyl Cross-Coupling with an Iron-Xantphos Catalyst: Mechanistic and Structural Insights
Magali Gimeno, Maria Camila Aguilera, Valerie Fleischauer,William Brennessel, and Michael Neidig
Angew. Chem. Int. Ed. 2024, e202413566
Unusual S = 1 Four-Coordinate Fe(IV) Complexes Supported by Bisamide Ligands: Syntheses, Characterization, and Electronic Structures
Zhang B, Joyce JP, Wolford N, Brennessel WW, DeBeer S, Neidig M
Angew. Chem. Int. Ed., 2024, e202405113
Ni(2,2':6',2''-terpyridine)2: a high-spin octahedral formal Ni(0) complex
Cabrera-Lobera N, Del Horno E, Quirós MT, Buñuel E, Gimeno M, Brennessel WW, Neidig ML, Priego JL, Cárdenas DJ
Dalton Trans., 2024, 53, 8550-8554
DOI: 10.1039/d3dt04247b
Mechanistic investigations of the Fe(II) mediated synthesis of squaraines
Liu, Y., Coles, N. T., Cajiao, N., Taylor, L. J.., Davies, E. S.; Barbour, A., Morgan, P., Butler, K.; Pointer-Gleadhill, B., Argent, S., McMaster, J., Neidig, M. L., Robinson, D., Kays, D. L.
Chem. Sci., 2024, 15, 9599-9611
DOI: 10.1039/d4sc01286k
Academia or Industry: Lessons on Choosing Career Paths─There May Be More Than One Fork in the Road Ahead
Blackmond DG, Emmert M, Huryn DM, Neidig ML, Schaub T, Topczewski JJ, Bravo-Altamirano K, Buchan Z, Cabrera PJ
Org. Lett., 2024, 26, 14, 2682–2685
Iron-catalyzed stereoselective C–H alkylation for simultaneous construction of C–N axial and C-central chirality
Zi-Jing Zhang, Nicolas Jacob, Shilpa Bhatia, Philipp Boos, Xinran Chen, Joshua C. DeMuth, Antonis M. Messinis, Becky Bongsuiru Jei, João C. A. Oliveira, Aleksa Radović, Michael L. Neidig, Joanna Wencel-Delord & Lutz Ackermann
Nature Communications, 2024, volume 15, 3503
Caught in the Act of Substitution: Interadsorbate Effects on an Atomically Precise Fe/Co/Se Nanocluster
Kephart JA, Zhou DY, Sandwisch J, Cajiao N, Krajewski SM, Malinowski P, Chu JH, Neidig ML, Kaminsky W, Velian A
ACS Cent. Sci. 2024
DOI: 10.1021/acscentsci.4c00210
Divergent Fe-Mediated C–H Activation Paths Driven by Alkali Cations
Vincent Wowk, Alexis K. Bauer, Aleksa Radovic, Lise-Marie Chamoreau, Michael L. Neidig, and Guillaume Lefèvre
JACS Au, 2024, 4, 2, 512–524
DOI: 10.1021/jacsau.3c00649
Mechanistic manifold in a hemoprotein-catalyzed cyclopropanation reaction with diazoketone
Donggeon Nam, John-Paul Bacik, Rahul L. Khade, Maria Camila Aguilera, Yang Wei, Juan D. Villada, Michael L. Neidig, Yong Zhang, Nozomi Ando & Rudi Fasan
Nature Communications, 2023, 14, 7985
DOI: 10.1038/s41467-023-43559-7
Palladium and Iron Cocatalyzed Aerobic Alkene Aminoboration
Gay, B. L., Wang, Y., Bhatt, S., Tarasewicz, A., Cooke, D. J., Milem, E. G., Zhang, B., Gary, J. B., Neidig, M. L., & Hull, K. L.
J. Am. Chem. Soc. 2023, 145, 18939–18947.
DOI: 10.1021/jacs.3c05790
Mechanistic Studies of Iron-PyBOX-Catalyzed Olefin Amino-Oxygenation with Functionalized Hydroxylamines
Radović, A.; Wolford, N. J.; Li, W.; Brennessel, W. W.; Xu, H.; Neidig, M. L.
Organometallics. 2023, 42, 1810–1817.
Insight into Radical Initiation, Solvent Effects, and Biphenyl Production in Iron–Bisphosphine Cross-Couplings
Aguilera, M. C.; Gogoi, A. R.; Lee, W.; Liu, L.; Brennessel, W. W.; Gutierrez, O.; Neidig, M. L.
ACS Catal. 2023, 13, 8987–8996.
Thermally Stable Redox Noninnocent Bathocuproine-Iron Complex for Cycloaddition Reactions
Féo, M.; Bakas, N. J.; Radović, A.; Parisot, W.; Clisson, A.; Chamoreau, L.; Mansour, Ratovelomanana-Vidal, V.,;Neidig, M. L.; Lefèvre, G.
ACS Catal. 2023, 13, 4882–4893.
The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts
Bakas, N. J.; Chourreu P.; Gayon, E.; Lefèvre, G.; Neidig, M. L.
Chem. Commun. 2023, 59, 1317-1320
DOI: 10.1039/D2CC06257G
Challenges and Opportunities of Fe-based Core-Shell Catalysts for Fischer-Tropsch Synthesis
Agwara, J. N.; Bakas, N. J.; Neidig, M. L.; & Porosoff, M. D.
ChemCatChem 2022, 14, e202200289.
Homoleptic Uranium–Bis(acyl)phosphide Complexes
Carpenter, S. H.; Wolford, N. J.; Billow, B. S.; Fetrow, T. V.; Cajiao, N.; Radović, A.; Janicke, M. T.; Neidig, M. L.; & Tondreau, A. M.
Inorg. Chem. 2022, 61, 12508–12517.
Anion-induced disproportionation of Th(III) complexes to form Th(II) and Th(IV) products
Wedal, J. C.; Cajiao, N.; Neidig, M. L.; & Evans, W. J.
Chem. Commun. 2022, 58, 5289-5291.
DOI: 10.1039/D2CC01272C
A TMEDA–Iron Adduct Reaction Manifold in Iron-Catalyzed C(sp2)−C(sp3) Cross-Coupling Reactions
Bakas, N. J.; Sears, J. D.; Brennessel, W. W.; Neidig M. L.
Angew. Chem. Int. Ed. 2022, 61, e202114986
Recent Advances in Synthesis, Characterization and Reactivities of Iron-Alkyl and Iron-Aryl Complexes
Zhang, B.; Aguilera, M.C.; Cajiao, N.; Neidig, M.L.
Comprehensive Organometallic Chemistry IV: Volume 1-15. 2022, 185–209
Characterization Methods for Paramagnetic Organometallic Complexes
Radović, A.; Bhatia, S.; Neidig, M.L.
Comprehensive Organometallic Chemistry IV: Volume 1-15. 2022, 135–175
Intermediates and mechanism in iron-catalyzed C–H methylation with trimethylaluminum
Bathia, S.; DeMuth, J.C.; Neidig M. L.
Chem. Commun. 2021, 57, 12784-12787
DOI: 10.1039/D1CC05607G
Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes
Gaiser, A. N.; Celis-Barros, C.; White, F. D.; Beltrán-Leiva, M. J.; Sperling, J.; Salpage, S. R.; Poe, T. N.; Martinez, D. G.; Jian, T., Wolford, N. J.; Neidig, M. L., & Albrecht‐Schönzart, T. E.; et al.
Nat Commun. 2021, 12, 7230
Air-Stable Iron-Based Precatalysts for Suzuki–Miyaura Cross-Coupling Reactions between Alkyl Halides and Aryl Boronic Esters
Wong, A. K. K.; Zhang, B.; Li, B.; Neidig, M. L.; & Byers, J. A.
Org. Process Res. Dev. 2021, 25, 2461–2472
General method for iron-catalyzed multicomponent radical cascades–cross-couplings
Liu, L.; Aguilera, M. C.; Lee, W.; Youshaw, C. R.; Neidig, M. L.; Gutierrez, O.
Science 2021, 374, 432–439
NHC Effects on Reduction Dynamics in Iron-Catalyzed Organic Transformations
Wolford, N. J.; Muñoz, S. B.; Neate, P. G. N.; Brennessel, W. W.; Neidig, M. L.
Chem. Eur. J. 2021, 27, 13651–13658
Cluster Supported by Redox-Active o-Phenylenediamide Ligands and Its Application toward Dinitrogen Reduction
Liang, Q.; DeMuth, J.; Radović, A.; Wolford, N. J.; Neidig, M. L.; & Song, D.
Inorg. Chem. 2021, 60, 13811–13820
An anionic iron-hydride superstar for the isomerization of terminal alkenes
Aguilera, M.C.; Neidig, M.L.
Chem Catal. 2021, 1, 488–489
Dilithium Amides as a Modular Bis-Anionic Ligand Platform for Iron-Catalyzed Cross-Coupling
Neate, P. G. N.; Zhang, B.; Conforti, J.; Brennessel, W. W.; Neidig, M. L.
Org. Lett. 2021, 23, 5958–5963
Metal-carbon bonds of iron and manganese
Neidig, M.L., Bakas, N.J., Neate, P.G.N., Sears, J.D.
Comprehensive Coordination Chemistry III. 2021, 82–122
C-H activation/functionalization with earth abundant 3d transition metals
Neidig, M.L., DeMuth, J.C., Zhang, B.
Comprehensive Coordination Chemistry III. 2021, 260–310
Experimental and computational studies of the mechanism of iron-catalysed C-H activation/functionalisation with allyl electrophiles
DeMuth, J. C.; Song, Z.; Carpenter, S. H.; Boddie, T. E.; Radović, A.; Baker, T. M.; Gutierrez, O.; Neidig, M. L.
Chem. Sci. 2021, 12, 9398–9407
DOI: 10.1039/D1SC01661J
Near-infrared C-term MCD spectroscopy of octahedral uranium(v) complexes
Curran, D. J.; Ganguly, G.; Heit, Y. N.; Wolford, N. J.; Minasian, S. G.; Löble, M. W.; Cary, S. K.; Kozimor, S. A.; Autschbach, J.; Neidig, M. L.
Dalton Trans. 2021, 50, 5483–5492
DOI: 10.1039/D1DT00513H
Forged in iron
Neate, P. G. N.; Neidig, M. L.
Nat Rev Chem. 2021, 5, 223–224
Activation of ammonia and hydrazine by electron rich Fe(II) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(III) amido intermediate
Nurdin, L.; Yang, Y.; Neate, P. G. N.; Piers, W. E.; Maron, L.; Neidig, M. L.; Lin, J.; Gelfand, B. S.
Chem. Sci. 2021,12, 2231-2241
DOI: 10.1039/D0SC06466A
C-Term Magnetic Circular Dichroism (MCD) Spectroscopy in Paramagnetic Transition Metal and f-Element Organometallic Chemistry
Wolford, N. J.; Radovic, A.; Neidig, M. L.
Dalton Trans. 2021, 50, 416–428
DOI: 10.1039/D0DT03730C
Additive and Counterion Effects in Iron-Catalyzed Reactions Relevant to C–C Bond Formation
Bakas, N. J.; Neidig, M. L.
ACS Catal. 2021, 11, 8493–8503
CHAPTER 7: Open Shell Iron Catalysis: Mechanistic Challenges, Approaches and Pitfalls
Neate, P.G.N.; Neidig, M.L.
RSC Catalysis Series. 2021, 231–245
Ligand Effects on Electronic Structure and Bonding in U(III) Coordination Complexes: A Combined MCD, EPR and Computational Study
Wolford, N. J.; Yu, X.; Bart, S. C.; Autschbach, J.; Neidig, M. L.
Dalton Trans. 2020, 49, 14401–14410
DOI: 10.1039/D0DT02929G
Syntheses and characterizations of iron complexes of bulky: O-phenylenediamide ligand
Liang, Q.; Lin, J.H.; Demuth, J.C.; Neidig, M.L.; Song, D.
Dalton Trans. 2020, 49, 12287-12297
DOI: 10.1039/D0DT02087G
TMEDA in Iron‐Catalyzed Hydromagnesiation: Formation of Iron(II)‐Alkyl Species for Controlled Reduction to Alkene‐Stabilized Iron(0)
Neate, P. G. N.; Greenhalgh, M. D.; Brennessel, W. W.; Thomas, S. P.; Neidig, M. L.
Angew. Chem. Int. Ed. 2020, 59, 17070–17076
The Exceptional Diversity of Homoleptic Uranium–Methyl Complexes
Sears, J. D.; Sergentu, D.; Baker, T. M.; Brennessel, W. W.; Autschbach, J.; Neidig, M. L.
Angew. Chem. Int. Ed. 2020, 59, 13586–13590
Identifying correlations in Fischer-Tropsch synthesis and CO2 hydrogenation over Fe-based ZSM-5 catalysts
Liu, R.; Ma, Z.; Sears, J. D.; Juneau, M.; Neidig, M. L.; Porosoff, M. D.
J. CO2 Util. 2020, 41, 101290
Isolation and Characterization of a Homoleptic Tetramethylcobalt(III) Distorted Square-Planar Complex
Carpenter, S.H.; Brennessel, W.W.; Neidig, M.L.
Organometallics 2019, 38, 3486–3489
Insight into the Electronic Structure of Formal Lanthanide(II) Complexes Using Magnetic Circular Dichroism Spectroscopy
Fleischauer, V. E.; Ganguly, G.; Woen, D. H.; Wolford, N. J.; Evans, W. J.; Autschbach, J.; Neidig, M. L.
Organometallics 2019, 38, 3124–3131
Atom-Economical Ni-Catalyzed Diborylative Cyclization of Enynes: Preparation of Unsymmetrical Diboronates
Cabrera‐Lobera, N., Quirós, M. T., Brennessel, W. W., Neidig, M. L., Buñuel, E., & Cárdenas, D. J.
Org. Lett. 2019, 21, 6552–6556
Identification and Reactivity of Cyclometalated Iron(II) Intermediates in Triazole-Directed Iron-Catalyzed C–H Activation
Boddie, T. E.; Carpenter, S. H.; Baker, T. M.; DeMuth, J. C.; Cera, G.; Brennessel, W. W.; Ackermann, L.; Neidig, M. L.
J. Am. Chem. Soc. 2019, 141, 12338–12345
DOI: 10.1021/jacs.9b05269
Homoleptic Aryl Complexes of Uranium (IV)
Wolford, N. J.; Sergentu, D.; Brennessel, W. W.; Autschbach, J.; Neidig, M. L.
Chem. Int. Ed. 2019, 58 (30), 10266–10270
Mechanism of the Bis(Imino)Pyridine-Iron-Catalyzed Hydromagnesiation of Styrene Derivatives
Neate, P. G. N.; Greenhalgh, M. D.; Brennessel, W. W.; Thomas, S. P.; Neidig, M. L.
J. Am. Chem. Soc. 2019, 141, 10099–10108
DOI: 10.1021/jacs.9b04869
The Effect of β‐Hydrogen Atoms on Iron Speciation in Cross‐Couplings with Simple Iron Salts and Alkyl Grignard Reagents
Sears, J. D.; Muñoz, S. B.; Daifuku, S. L.; Shaps, A. A.; Carpenter, S. H.; Brennessel, W. W.; Neidig, M. L.
Angew. Chem. Int. Ed. 2019, 58, 2769–2773
Development and Evolution of Mechanistic Understanding in Iron-Catalyzed Cross-Coupling
Neidig, M. L.; Carpenter, S. H.; Curran, D. J.; DeMuth, J. C.; Fleischauer, V. E.; Iannuzzi, T. E.; Neate, P. G. N.; Sears, J. D.; Wolford, N. J.
Acc. Chem. Res. 2019, 52, 140–150
Synthesis and Characterization of a Sterically Encumbered Homoleptic Tetraalkyliron(III) Ferrate Complex
Sears, J. D.; Muñoz, S. B.; Cuenca, M. C. A.; Brennessel, W. W.; Neidig, M. L.
Polyhedron 2019, 158, 91–96
Terminal Coordination of Diatomic Boron Monofluoride to Iron
Drance, M. J.; Sears, J. D.; Mrse, A. M.; Moore, C. E.; Rheingold, A. L.; Neidig, M. L.; Figueroa, J. S.
Science 2019, 363, 1203–1205
Crystal structure of bromidopentakis(tetrahydrofuran-κ O)magnesium bis[1,2-bis(diphenylphosphanyl)benzene-κ2P, P ′]cobaltate(-1) tetrahydrofuran disolvate
Girigiri, P.B.; Carpenter, S.H.; Brennessel, W.W.; Neidig, M.L.
Acta Crystallogr. E: Crystallogr. Commun. 2019, 75, 304–307
Intermediates and Mechanism in Iron-Catalyzed Cross-Coupling
Sears, J. D.; Neate, P. G. N.; Neidig, M. L.
J. Am. Chem. Soc. 2018, 140 (38), 11872–11883
DOI: 10.1021/jacs.8b06893
Combined Effects of Backbone and N-Substituents on Structure, Bonding, and Reactivity of Alkylated Iron(II)-NHCs
Muñoz, S. B.; Fleischauer, V. E.; Brennessel, W. W.; Neidig, M. L.
Organometallics 2018, 37, 3093–3101
Backbone Dehydrogenation in Pyrrole-Based Pincer Ligands
Krishnan, V. M.; Davis, I.; Baker, T. M.; Curran, D. J.; Arman, H. D.; Neidig, M. L.; Liu, A.; Tonzetich, Z. J.
Inorg. Chem. 2018, 57, 9544–9553
A Pseudotetrahedral Uranium(V) Complex
Tondreau, A. M.; Duignan, T. J.; Stein, B. W.; Fleischauer, V. E.; Autschbach, J.; Batista, E. R.; Boncella, J. M.; Ferrier, M. G.; Kozimor, S. A.; Mocko, V.; Neidig, M. L.; Cary, S. K.; Yang, P.
Inorg. Chem. 2018, 57, 8106–8115
The N-Methylpyrrolidone (NMP) Effect in Iron‐Catalyzed Cross‐Coupling with Simple Ferric Salts and MeMgBr
Muñoz, S. B.; Daifuku, S. L.; Sears, J. D.; Baker, T. M.; Carpenter, S. H.; Brennessel, W. W.; Neidig, M. L.
Chem. Int. Ed. 2018, 57, 6496
NHC and Nucleophile Chelation Effects on Reactive Iron(II) Species in Alkyl–Alkyl Cross-Coupling
Fleischauer, V. E.; Muñoz III, S. B.; Neate, P. G. N.; Brennessel, W. W.; Neidig, M. L.
Chem. Sci. 2018, 9, 1878–1891
DOI: 10.1039/C7SC04750A
Multinuclear Iron–Phenyl Species in Reactions of Simple Iron Salts with PhMgBr: Identification of Fe4(μ-Ph)6(THF)4
Carpenter, S. H.; Baker, T. M.; Muñoz, S. B.; Brennessel, W. W.; Neidig, M. L.
Chem. Sci. 2018, 9, 7931–7939
DOI: 10.1039/C8SC02915F
Nitric Oxide Activation Facilitated by Cooperative Multimetallic Electron Transfer within an Iron-Functionalized Polyoxovanadate–Alkoxide Cluster
Li, F.; Meyer, R. L.; Carpenter, S. H.; VanGelder, L. E.; Nichols, A. W.; Machan, C. W.; Neidig, M. L.; Matson, E.
Chem. Sci. 2018, 9, 6379–6389
DOI: 10.1039/C8SC00987B
Crystal structures of two new six-coordinate iron(III) complexes with 1,2-bis(diphenylphosphane) ligands
McNeil, D. L., Beckford, D. J., Kneebone, J. L., Carpenter, S. H., Brennessel, W. W., & Neidig, M. L.
Acta Crystallogr. E: Crystallogr. Commun. 2018, 74, 803–807
A Physical-Inorganic Approach for the Elucidation of Active Iron Species and Mechanism in Iron-Catalyzed Cross-Coupling
Carpenter, S. H.; Neidig, M. L.
Isr. J. Chem. 2017, 57, 1106–1116
Iron(II) Complexes of a Hemilabile SNS Amido Ligand: Synthesis, Characterization, and Reactivity
Das, U. K.; Daifuku, S. L.; Iannuzzi, T. E.; Gorelsky, S. I.; Korobkov, I.; Gabidullin, B.; Neidig, M. L.; Baker, R. T.
Inorg. Chem. 2017, 56, 13766–13776
A Combined Probe-Molecule, Mössbauer, Nuclear Resonance Vibrational Spectroscopy, and Density Functional Theory Approach for Evaluation of Potential Iron Active Sites in an Oxygen Reduction Reaction Catalyst
Kneebone, J. L.; Daifuku, S. L.; Kehl, J. A.; Wu, G.; Chung, H. T.; Hu, M. Y.; Alp, E. E.; More, K. L.; Zelenay, P.; Holby, E. F.; Neidig, M. L.
J. Phys. Chem. C. 2017, 121, 16283–16290
Polyoxovanadate–Alkoxide Clusters as a Redox Reservoir for Iron
Li, F.; Carpenter, S. H.; Higgins, R. F.; Hitt, M. G.; Brennessel, W. W.; Ferrier, M. G.; Cary, S. K.; Lezama-Pacheco, J. S.; Wright, J. T.; Stein, B. W.; Shores, M. P.; Neidig, M. L.; Kozimor, S. A.; Matson, E. M.
Inorg. Chem. 2017, 56, 7065–7080
Intermediates and Reactivity in Iron-Catalyzed Cross-Couplings of Alkynyl Grignards with Alkyl Halides
Kneebone, J. L.; Brennessel, W. W.; Neidig, M. L.
J. Am. Chem. Soc. 2017, 139, 6988–7003
DOI: 10.1021/jacs.7b02363
Transition-Metal-Free Formation of C–E Bonds (E = C, N, O, S) and Formation of C–M Bonds (M = Mn, Mo) from N -Heterocyclic Carbene Mediated Fluoroalkene C–F Bond Activation
Leclerc, M. C.; Gabidullin, B. M.; Da Gama, J. G.; Daifuku, S. L.; Iannuzzi, T. E.; Neidig, M. L.; Baker, R. T.
Organometallics 2017, 36, 849–857
Magnetic Circular Dichroism and Density Functional Theory Studies of Electronic Structure and Bonding in Cobalt(II)–N-Heterocyclic Carbene Complexes
Iannuzzi, T. E.; Gao, Y.; Baker, T. M.; Deng, L.; Neidig, M. L.
Dalton Trans. 2017, 46, 13290–13299
DOI: 10.1039/C7DT01748K
Magnetic Circular Dichroism of UCl6− in the Ligand-to-Metal Charge-Transfer Spectral Region
Gendron, F.; Fleischauer, V. E.; Duignan, T. J.; Scott, B. L.; Löble, M. W.; Cary, S. K.; Kozimor, S. A.; Bolvin, H.; Neidig, M. L.; Autschbach, J.
Phys. Chem. Chem. Phys. 2017, 19, 17300–17313
DOI: 10.1039/C7CP02572F
Magnetic Circular Dichroism Studies of Iron(II) Binding to Human Calprotectin
Baker, T. M.; Nakashige, T. G.; Nolan, E. M.; Neidig, M. L.
Chem. Sci. 2017, 8, 1369–1377
DOI: 10.1039/C6SC03487J
Magnetic Circular Dichroism and Density Functional Theory Studies of Iron(II)-Pincer Complexes: Insight into Electronic Structure and Bonding Effects of Pincer N-Heterocyclic Carbene Moieties
Baker, T. M.; Mako, T. L.; Vasilopoulos, A.; Li, B.; Byers, J. A.; Neidig, M. L.
Organometallics 2016, 35, 3692–3700
Resident Holes and Electrons at Organic/Conductor and Organic/Organic Interfaces: An Electron Paramagnetic Resonance Investigation
Zhang, C.; Daifuku, S. L.; Neidig, M. L.; Marchetti, A. P.
Org. Electron. 2016, 37, 379–385
Catalytic Light-Driven Generation of Hydrogen from Water by Iron Dithiolene Complexes
Lv, H.; Ruberu, T. P. A.; Fleischauer, V. E.; Brennessel, W. W.; Neidig, M. L.; Eisenberg, R.
J. Am. Chem. Soc. 2016, 138, 11654–11663
DOI: 10.1021/jacs.6b05040
Manipulating Magneto-Optic Properties of a Chiral Polymer by Doping with Stable Organic Biradicals
Lim, C.-K.; Cho, M. J.; Singh, A.; Li, Q.; Kim, W. J.; Jee, H. S.; Fillman, K. L.; Carpenter, S. H.; Neidig, M. L.; Baev, A.; Swihart, M. T.; Prasad, P. N.
Nano Lett. 2016, 16, 5451–5455
Isolation, Characterization, and Reactivity of Fe8Me12– : Kochi’s S = 1/2 Species in Iron-Catalyzed Cross-Couplings with MeMgBr and Ferric Salts
Muñoz, S. B.; Daifuku, S. L.; Brennessel, W. W.; Neidig, M. L.
J. Am. Chem. Soc. 2016, 138, 7492–7495
DOI: 10.1021/jacs.6b03760
Mononuclear, Dinuclear, and Trinuclear Iron Complexes Featuring a New Monoanionic SNS Thiolate Ligand
Das, U. K.; Daifuku, S. L.; Gorelsky, S. I.; Korobkov, I.; Neidig, M. L.; Le Roy, J. J.; Murugesu, M.; Baker, R. T.
Inorg. Chem. 2016, 55, 987–997
Electronic Structure and Bonding in Iron(II) and Iron(I) Complexes Bearing Bisphosphine Ligands of Relevance to Iron-Catalyzed C–C Cross-Coupling
Kneebone, J. L.; Fleischauer, V. E.; Daifuku, S. L.; Shaps, A. A.; Bailey, J. M.; Iannuzzi, T. E.; Neidig, M. L.
Inorg. Chem. 2016, 55, 272–282
Facile Hydrogen Atom Transfer to Iron(III) Imido Radical Complexes Supported by a Dianionic Pentadentate Ligand
Spasyuk, D. M.; Carpenter, S. H.; Kefalidis, C. E.; Piers, W. E.; Neidig, M. L.; Maron, L.
Chem. Sci. 2016, 7, 5939–5944
DOI: 10.1039/C6SC01433J
Possible Demonstration of a Polaronic Bose-Einstein(-Mott) Condensate in UO2(+x) by Ultrafast THz Spectroscopy and Microwave Dissipation
Conradson, S. D.; Gilbertson, S. M.; Daifuku, S. L.; Kehl, J. A.; Durakiewicz, T.; Andersson, D. A.; Bishop, A. R.; Byler, D. D.; Maldonado, P.; Oppeneer, P. M.; Valdez, J. A.; Neidig, M. L.; Rodriguez, G.
Sci Rep 2015, 5, 15278
DOI: 10.1038/srep15278
Iron(II) Active Species in Iron–Bisphosphine Catalyzed Kumada and Suzuki–Miyaura Cross-Couplings of Phenyl Nucleophiles and Secondary Alkyl Halides
Daifuku, S. L.; Kneebone, J. L.; Snyder, B. E. R.; Neidig, M. L.
J. Am. Chem. Soc. 2015, 137, 11432–11444
DOI: 10.1021/jacs.5b06648
Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization
Ouyang, Z.; Du, J.; Wang, L.; Kneebone, J. L.; Neidig, M. L.; Deng, L.
Inorg. Chem. 2015, 54, 8808–8816
Ambivalent Binding between a Radical-Based Pincer Ligand and Iron
Harriman, K. L. M.; Leitch, A. A.; Stoian, S. A.; Habib, F.; Kneebone, J. L.; Gorelsky, S. I.; Korobkov, I.; Desgreniers, S.; Neidig, M. L.; Hill, S.; Murugesu, M.; Brusso, J. L.
Dalton Trans. 2015, 44, 10516–10523
DOI: 10.1039/C5DT01374G
How Innocent Are Potentially Redox Non-Innocent Ligands? Electronic Structure and Metal Oxidation States in Iron-PNN Complexes as a Representative Case Study
Butschke, B.; Fillman, K. L.; Bendikov, T.; Shimon, L. J. W.; Diskin-Posner, Y.; Leitus, G.; Gorelsky, S. I.; Neidig, M. L.; Milstein, D.
Inorg. Chem. 2015, 54, 4909–4926
A Combined Magnetic Circular Dichroism and Density Functional Theory Approach for the Elucidation of Electronic Structure and Bonding in Three- and Four-Coordinate Iron(II)–N-Heterocyclic Carbene Complexes
Fillman, K. L.; Przyojski, J. A.; Al-Afyouni, M. H.; Tonzetich, Z. J.; Neidig, M. L.
Chem. Sci. 2015, 6, 1178–1188
DOI: 10.1039/C4SC02791D
Crystal structure of a third polymorph of tris(acetylacetonato-κ2O,O')iron(III)
Baker, T.M., Howard, K.M., Brennessel, W.W., Neidig, M.L.
Acta Crystallogr. E: Crystallogr. Commun. 2015, 71, m228–m229
Isolation and Characterization of a Tetramethyliron(III) Ferrate: An Intermediate in the Reduction Pathway of Ferric Salts with MeMgBr
Al-Afyouni, M. H.; Fillman, K. L.; Brennessel, W. W.; Neidig, M. L.
J. Am. Chem. Soc. 2014, 136, 15457–15460
DOI: 10.1021/ja5080757
Two- and Three-Coordinate Formal Iron(I) Compounds Featuring Monodentate Aminocarbene Ligands
Mo, Z.; Ouyang, Z.; Wang, L.; Fillman, K. L.; Neidig, M. L.; Deng, L.
Org. Chem. Front. 2014, 1, 1040–1044
DOI: 10.1039/C4QO00175C
Iron Phosphine Catalyzed Cross-Coupling of Tetraorganoborates and Related Group 13 Nucleophiles with Alkyl Halides
Bedford, R. B.; Brenner, P. B.; Carter, E.; Clifton, J.; Cogswell, P. M.; Gower, N. J.; Haddow, M. F.; Harvey, J. N.; Kehl, J. A.; Murphy, D. M.; Neeve, E. C.; Neidig, M. L.; Nunn, J.; Snyder, B. E. R.; Taylor, J.
Organometallics 2014, 33, 5767–5780
DOI: 10.1021/om500518r
A Combined Mössbauer, Magnetic Circular Dichroism, and Density Functional Theory Approach for Iron Cross-Coupling Catalysis: Electronic Structure, In Situ Formation, and Reactivity of Iron-Mesityl-Bisphosphines
Daifuku, S. L.; Al-Afyouni, M. H.; Snyder, B. E. R.; Kneebone, J. L.; Neidig, M. L.
J. Am. Chem. Soc. 2014, 136 (25), 9132–9143
DOI: 10.1021/ja503596m
Flexible Binding of PNP Pincer Ligands to Monomeric Iron Complexes
Fillman, K. L.; Bielinski, E. A.; Schmeier, T. J.; Nesvet, J. C.; Woodruff, T. M.; Pan, C. J.; Takase, M. K.; Hazari, N.; Neidig, M. L.
Inorg. Chem. 2014, 53, 6066–6072
DOI: 10.1021/ic5004275
Iron Dicarbonyl Complexes Featuring Bipyridine-Based PNN Pincer Ligands with Short Interpyridine C-C Bond Lengths: Innocent or Non-Innocent Ligand?
Zell, T.; Milko, P.; Fillman, K. L.; Diskin-Posner, Y.; Bendikov, T.; Iron, M. A.; Leitus, G.; Ben-David, Y.; Neidig, M. L.; Milstein, D.
Chem. Eur. J. 2014, 20, 4403–4413
Reactivity of (NHC)2FeX2 Complexes toward Arylborane Lewis Acids and Arylboronates
Dunsford, J. J.; Cade, I. A.; Fillman, K. L.; Neidig, M. L.; Ingleson, M. J.
Organometallics 2014, 33, 370–377
DOI: 10.1021/om401105k
Direct Observation of ICT Cations at the HTL/Transparent Semiconductor Interface
Daifuku, S. L.; Favaro, C.; Marchetti, A. P.; Neidig, M. L.
Org. Chem. Front. 2014, 15, 3761–3765
Efficient Nazarov Cyclization/Wagner-Meerwein Rearrangement Terminated by a CuII-Promoted Oxidation: Synthesis of 4-Alkylidene Cyclopentenones
Lebœuf, D.; Theiste, E.; Gandon, V.; Daifuku, S. L.; Neidig, M. L.; Frontier, A. J.
Chem. Eur. J. 2013, 19, 4842–4848
Covalency in F-Element Complexes
Neidig, M. L.; Clark, D. L.; Martin, R. L.
Coord. Chem. Rev. 2013, 394–406
Covalency in F-Element Complexes
Neidig, M. L.; Clark, D. L.; Martin, R. L.
Coord. Chem. Rev. 2013, 394–406
DOI: 10.1016/j.ccr.2012.04.029
